Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 33, Pages 9728-9732Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604182
Keywords
alkynes; copper; cycloadditions; enantioselectivity; synthetic methods
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Funding
- CREST from JST
- JSPS [26288044, 26105708, 15K13687, 15H05798]
- MEXT
- Grants-in-Aid for Scientific Research [15H05798, 26288044, 26105708, 15K13687] Funding Source: KAKEN
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Copper-catalyzed enantioselective propargylation of indoles with propargylic esters and sequential Huisgen cycloaddition with azides lead to the construction of chiral triarylmethanes, bearing a quaternary carbon center, with high to excellent enantioselectivities. The result described herein can be used in the enantioselective preparation of a tetraarylmethane.
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