Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 11, Pages 3657-3661Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511100
Keywords
boronic esters; chlorides; cyclopropanation; homologation; hydroboration
Categories
Funding
- China Scholarship Council (CSC)
- Swiss National Science Foundation [200020_152782, 206021_128724]
- Swiss National Science Foundation (SNF) [206021_128724, 200020_152782] Funding Source: Swiss National Science Foundation (SNF)
Ask authors/readers for more resources
An intramolecular cyclopropanation reaction involving B-(1-chloroalkyl)catecholborane intermediates generated from 1,4-dienes through hydroboration with catecholborane and Matteson homologation was developed. This sequential procedure leading to bicyclo[3.1.0]hexanes involves the formation of three new sigma C-C bonds at the same carbon atom. A mechanistic study supports the involvement of carbocationic intermediates.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available