Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 33, Pages 9474-9480Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201602116
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Funding
- 973 program [2012CB821705, 2013CB933203]
- NSFC [21331006, 21520102001]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030102]
- Royal Society
- Sino-British Fellowship Trust (RS-SBFT)
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The assembly of porous organic molecular frameworks (POMFs), which typically evidence common feasibility and compatibility, purification, and regeneration at practical conditions, remains a strategic challenge in modern materials science and is crucial for their favorable applications in biological, medical, and environmental realms. However, instructive knowledge of well-organized POMF assembly by supramolecular interactions is, in general, ambiguous to date. Nevertheless, a significant advance in controlled POMF assembly has been recently achieved. This Minireview highlights these approaches, with a particular focus on the design of molecular constituents and assembly strategies. We also look beyond the field of solid-state POMF materials into the assembly and recognition in solution, thus covering recent advances in POMFs based on material design and applications in carbon storage and separation.
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