Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 2, Pages 563-567Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610914
Keywords
heterogeneous catalysis; hierarchically porous materials; large molecules; metal-organic frameworks; stability
Categories
Funding
- NSFC [21371162, 21673213, 21521001, 51301159]
- 973 program [2014CB931803]
- NSF of Anhui Province [1408085MB23]
- Recruitment Program of Global Youth Experts
- Fundamental Research Funds for the Central Universities [WK2060190026, WK2060190065]
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The pore size enlargement and structural stability have been recognized as two crucial targets, which are rarely achieved together, in the development of metal-organic frameworks (MOFs). Herein, we have developed a versatile modulator- induced defect-formation strategy, in the presence of monocarboxylic acid as a modulator and an insufficient amount of organic ligand, successfully realizing the controllable synthesis of hierarchically porous MOFs (HP-MOFs) with high stability and tailorable pore characters. Remarkably, the integration of high stability and large mesoporous property enables these HP-MOFs to be important porous platforms for applications involving large molecules, especially in catalysis.
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