Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 31, Pages 8923-8927Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603149
Keywords
C-H activation; fluorination; hydrogen atom transfer; photocatalysis; uranium
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Funding
- NIGMS [R01 GM065483]
- NSF-GRFP [DGE 1148900]
- NSF-CCI Center for Selective C-H Functionalization [CHE-1205646]
- Princeton University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1205646] Funding Source: National Science Foundation
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The fluorination of unactivated C(sp(3)) -H bonds remains a desirable and challenging transformation for pharmaceutical, agricultural, and materials scientists. Previous methods for this transformation have used bench-stable fluorine atom sources; however, many still rely on the use of UV-active photocatalysts for the requisite high-energy hydrogen atom abstraction event. Uranyl nitrate hexahydrate is described as a convenient, hydrogen atom abstraction catalyst that can mediate fluorinations of certain alkanes upon activation with visible light.
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