Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 10, Pages 3477-3480Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510912
Keywords
dimerization; halocarbon compounds; halogen bonding; molecular recognition; self-assembly
Categories
Funding
- National Science Foundation [LRM DMR-1408834]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1408834] Funding Source: National Science Foundation
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A ditopic halogen-bond acceptor organizes a diiodooctafluorostilbene for a [2+2] photodimerization reaction to take place between two stilbene molecules in the solid state. The resultant cyclobutane product is functionalized with halogen atoms and undergoes self-assembly to form a channel-type host-guest compound that exhibits a very rare form of self-inclusion.
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