Journal
CHEMPLUSCHEM
Volume 84, Issue 4, Pages 319-322Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201800563
Keywords
energetic materials; eutectic technology; explosives; heterocycles; organic synthesis
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Funding
- U.S. Army
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A scalable synthesis of bis(1,2,4-oxadiazoyl) furoxan, C6H2N6O4, its physical properties, and its theoretical performance values are described. Previous attempts to synthesize this compound required expensive reagents, and/or time-consuming synthesis processes and low overall yields. In addition to disclosing a streamlined synthesis of bis(1,2,4-oxadiazolyl) furoxan, we report its molecular configuration and crystal structure, as well as its correct melting point. Bis(1,2,4-oxadiazolyl) furoxan exhibits a very insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure 20% higher than that of TNT. Given its physical properties and theoretical performance values, this material can be classified as a promising ingredient in the development of melt-castable eutectic technology.
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