Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 23, Pages 6671-6675Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601197
Keywords
alkenes; cobalt; homogeneous catalysis; hydrosilylation; iron
Categories
Funding
- National Basic Research Program of China [2015CB856600]
- National Natural Science Foundation of China [21422209, 21432011, 21421091]
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A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of phosphine-iminopyridine are selective for anti-Markovnikov hydrosilylations (linear/branched up to > 99:1), while the cobalt complexes bearing the same type of ligands provide an unprecedented high level of Markovnikov selectivity (branched/linear up to > 99:1). Both systems exhibit high efficiency and wide functional group tolerance.
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