Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 8, Pages 2920-2924Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510738
Keywords
catalyst recycling; homogeneous catalysis; hydroformylation; process development; thermomorphic solvent systems
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
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A new process concept has been developed for recycling transition-metal catalysts in the synthesis of moderately polar products via aqueous thermomorphic multicomponent solvent systems. This work focuses on the use of green solvents (1-butanol and water) in the hydroformylation of the bio-based substrate methyl 10-undecenoate. Following the successful development of a biphasic reaction system on the laboratory scale, the reaction was transferred to a continuously operated miniplant to demonstrate the robustness of this innovative recycling concept for homogenous catalysts.
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