Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 28, Pages 8121-8124Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601767
Keywords
density functional theory; disulfate; palladium; structure elucidation; vibrational spectroscopy
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Funding
- Deutsche Forschungsgemeinschaft
- Stiftung der Metallindustrie im Nord-Westen
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For the first time tetravalent palladium is detected, coordinated exclusively by simple oxoanions. Stabilization was achieved by formation of the [Pd(S2O7)(3)](2-) complex in which three chelating disulfate groups surround the metal atom. The salt K-2[Pd(S2O7)(3)] could only be obtained if the reaction of K-2[PdCl6] and neat SO3 was performed in the presence of XeF2.
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