Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 51, Pages 15807-15811Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201609468
Keywords
decarboxylation; fluorine; radicals; reaction mechanisms; synthetic methods
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Funding
- National Natural Science Foundation of China [21632009, 21372247, 21572258, 21572259, 21421002]
- SIOC
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A new shelf-stable and easily scalable difluoromethylthiolating reagent S-(difluoromethyl) benzenesulfonothioate (PhSO2SCF2H) was developed. PhSO2SCF2H is a powerful reagent for radical difluoromethylthiolation of aryl and alkyl boronic acids, decarboxylative difluoromethylthiolation of aliphatic acids, and a phenylsulfonyl-difluoromethylthio difunctionalization of alkenes under mild reaction conditions.
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