4.8 Article

UV-Induced Disulfide Formation and Reduction for Dynamic Photopatterning

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 44, Pages 13765-13769

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607276

Keywords

disulfide formation; disulfide reduction; dynamic photopatterning; photochemistry; surface modification

Funding

  1. Helmholtz Association's Initiative and Networking Fund [VH-NG-621]
  2. European Research Council [ERC-2013-StG 337077-DropCellArray]

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UV-induced disulfide formation (UV-DF) and disulfide reduction (UV-DR) reactions for surface functionalization and dynamic photopatterning are presented. Both photochemical reactions allow for the spatially and temporally controlled, reversible transition between thiol-and disulfidefunctionalized surfaces. The dynamic photopatterning strategy was demonstrated by the UV-induced attachment, exchange, and detachment on thiol-modified substrates.

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