Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 3, Pages 880-884Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610453
Keywords
aggregation-induced emission; fluorescence; mechanoluminescence; phosphorescence
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Funding
- National Fundamental Key Research Program [2013CB834701]
- National Science Foundation of China [21325416, 51573140]
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We report the first example of an AIEgen (DPPBO) with fluorescence-phosphorescence dual emission under mechanical stimulation. By carefully analyzing the crystal structure of DPP-BO, the efficient intermolecular and intramolecular interactions should account for its unique mechanoluminescence (ML) properties, especially the abnormal phosphorescence, as further confirmed by controlled experiments and theoretical calculations for the presence of ISC transitions. These results provide important information for understanding the complex ML process, possibly opening up a new way to study the inherent mechanism of ML by broadening the application of AIEgens.
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