Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 39, Pages 11726-11735Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603697
Keywords
fluorine; hypervalent iodine compounds; synthetic methods trifluoromethoxide; trifluoromethoxylation
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Ecole Superieure Chimie Physique Electronique de Lyon (CPE Lyon)
- French Fluorine Network
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Because of the unique properties of the trifluoromethoxy group, molecules bearing this moiety will find applications in various fields, particularly in the life sciences. However, despite the great interest in this functional group, only a small number of trifluoromethoxylated molecules are currently synthetically accessible. Over the last few years, several innovative and promising strategies for the synthesis of trifluoromethoxylated compounds have been described. This Minireview discusses these existing methods with a particular focus on more recent advances.
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