Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 42, Pages 13072-13075Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201606707
Keywords
carbide; C-H bond activation; gas-phase reactions; hydride transfer
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
- DFG
- Fonds der Chemischen Industrie
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The reactivity of the cationic gold carbide [AuC](+) (bearing an electrophilic carbon atom) towards methane has been studied using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). The product pairs generated, that is, Au+/C2H4, [Au(C2H2)](+)/H-2, and [C2H3](+)/AuH, point to the breaking and making of C-H, C-C, and H-H bonds under single-collision conditions. The mechanisms of these rather efficient reactions have been elucidated by high-level quantum chemical calculations. As a major result, based on molecular orbital and NBO-based charge analysis, an unprecedented hydride transfer from methane to the carbon atom of [AuC](+) has been identified as a key step. Also, the origin of this novel mechanistic scenario has been addressed. The mechanistic insights derived from this study may provide guidance for the rational design of carbon-based catalysts.
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