4.6 Article

Coplanar Donor-π-Acceptor Dyes Featuring a Furylethynyl Spacer for Dye-Sensitized Solar Cells

Journal

MATERIALS
Volume 12, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/ma12050839

Keywords

dye-sensitized solar cell; donor--acceptor; furyethynyl; density functional theory

Funding

  1. Technology Advancement Research Program (TARP) - Ministry of Land, Infrastructures, and Transport (MOLIT) of Korea [18CTAPC-C129910-02]
  2. National Research Foundation of Korea (NRF) Grant - Ministry of Science and ICT for First-Mover Program for Accelerating Disruptive Technology Development [NRF-2018M3C1B9088457]

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Coplanar metal-free organic dyes featuring a furylethynyl spacer with different donor residues (MeO-, MeS-, and Me2N-) have been synthesized. Density functional theory (DFT) calculations predicted that the Me2N- residue would facilitate more effective charge transfer from donor to acceptor than the MeO- and MeS- residues. In agreement with DFT calculations, the dye-sensitized solar cells (DSSCs) fabricated with the Me2N- functionalized dye exhibited the best power conversion efficiency (), 2.88%. Furthermore, the effect of the furan spacer on the photophysical properties and DSSC parameters are discussed in comparison to a previously reported thiophene counterpart.

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