Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 49, Pages 15246-15249Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608955
Keywords
asymmetric amplification; asymmetric autocatalysis; chirality; isotopes; nitrogen isotopes
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Funding
- Japan Society for the Promotion of Science (JSPS KAKENHI Grant) [23685012, 26810026, 15H03781]
- MEXT
- Grants-in-Aid for Scientific Research [26810026, 23685012, 16K05692] Funding Source: KAKEN
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Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a chemical reaction. An N-2,N-2,N-3,N-3-tetramethyl-2,3-butanediamine containing nitrogen (N-14/N-15) isotope chirality was synthesized and it was revealed that this isotopically chiral diamine compound acts as a chiral initiator for asymmetric autocatalysis.
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