Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 3, Pages 851-855Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201609844
Keywords
alkenes; copper; cross-coupling; enantioselective catalysis; palladium
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Funding
- Indiana University
- National Institutes of Health [1R01GM114443]
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A method for the catalytic enantioselective arylboration of alkenylarenes is disclosed. The reaction leads to the formation of 1,1-diarylalkanes that also incorporate an additional pinacol boronic ester which can be easily transformed to a variety of groups. The products are formed with excellent diastereoselectivities and enantioselectivities.
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