Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 8, Pages 2743-2747Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510533
Keywords
fluorine; isocyanides; photoredox catalysis; radical reactions; sulfones
Categories
Funding
- National Basic Research Program of China [2015CB931900, 2012CB821600]
- National Natural Science Foundation of China [21372246, 21421002, 21472221]
- Chinese Academy of Sciences, Shanghai Science and Technology program [15XD1504400]
- Syngenta Ph.D. Studentship
Ask authors/readers for more resources
The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible-light photoredox catalysis. A wide range of readily available mono-, di-, and trifluoromethyl heteroaryl sulfones can thus be used as efficient radical fluoroalkylation reagents under mild conditions. This method not only describes a new synthetic application of fluorinated sulfones, but also provides a new route to fluoroalkyl radicals.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available