Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 19, Pages 5749-5753Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201600267
Keywords
coordination modes; nanoalloys; nanoclusters; photoluminescence; supramolecular chemistry
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Funding
- KAUST
- Saudi Arabia Basic Industries Corporation (SABIC) [RGC/3/2470-01, GIF/5/1830-01]
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A high quantum yield (QY) of photoluminescence (PL) in nanomaterials is necessary for a wide range of applications. Unfortunately, the weak PL and moderate stability of atomically precise silver nanoclusters (NCs) suppress their utility. Herein, we accomplished a 26-fold PL QY enhancement of the Ag-29(BDT)(12)(TPP)(4) cluster (BDT: 1,3-benzenedithiol; TPP: triphenylphosphine) by doping with a discrete number of Au atoms, producing Ag29-xAux(BDT)(12)(TPP)(4), x=1-5. The Au-doped clusters exhibit an enhanced stability and an intense red emission around 660nm. Single-crystal XRD, mass spectrometry, optical, and NMR spectroscopy shed light on the PL enhancement mechanism and the probable locations of the Au dopants within the cluster.
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