Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 43, Pages 13504-13508Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607455
Keywords
cellulose; CuO nanoparticles; heterogeneous structures; hollow fibers; pyrolysis
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Funding
- National Natural Science Foundation of China [51273151, 51473128]
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A facile method for the fabrication of inorganic hollow materials from cuprammonium cellulose composite filaments based on fast pyrolysis has been developed. Unlike Ostwald ripening, approaches based on the Kirkendall effect, and other template methods, this process yielded hollow materials within 100s. The heterogeneous structure of the cellulose composite fibers and the gradient distribution of the metal oxides are the main reasons for the formation of the hollow structure. The diameter, wall thickness, and length of the hollow microfibers could be conveniently controlled. With their perfect morphology, these hollow structural materials have great potential for use in various fields.
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