4.8 Article

Mesoporous Manganese Oxide Catalyzed Aerobic Oxidative Coupling of Anilines To Aromatic Azo Compounds

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 6, Pages 2171-2175

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508223

Keywords

aniline oxidation; azo compounds; heterogeneous catalysis; manganese oxide; mesoporous materials

Funding

  1. US Department of Energy, Office of Basic Energy Sciences, Division of Chemical, Biological and Geological Sciences [DE-FG02-86ER13622.A000]
  2. University of New Haven

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Herein we introduce an environmentally friendly approach to the synthesis of symmetrical and asymmetrical aromatic azo compounds by using air as the sole oxidant under mild reaction conditions in the presence of cost-effective and reusable mesoporous manganese oxide materials.

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