Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 38, Pages 11673-11677Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604001
Keywords
charge density; coupling constants; MO analysis; NMR spectroscopy; nonclassical silane complexes
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Funding
- DFG [SPP1178, SCHE478/9-3]
- DGSCA, UNAM [SC15-1-IR-66]
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We will outline that the sign and magnitude of J(Si,H) coupling constants provide a highly sensitive tool to measure the extent of Si-H bond activation in nonclassical silane complexes. Up to now, this structure-property relationship was obscured by erroneous J(Si,H) sign determinations in the literature. These new findings also help to identify the salient control parameters of the Si-H bond activation process in nonclassical silane complexes.
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