Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 16, Pages 5049-5052Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201600591
Keywords
enantioselective synthesis; iridium; polyketide; total synthesis; transfer hydrogenation
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Funding
- Robert A. Welch Foundation [F-0038]
- NIH [RO1-GM093905]
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The polyketide natural product cryptocaryolA is prepared in 8 steps via iridium catalyzed enantioselective diol double C-H allylation, which directly generates an acetate-based triketide stereodiad. In 4 previously reported total syntheses, 17-28 steps were required.
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