Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 16, Pages 4997-5002Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601004
Keywords
catalysis; olefin metathesis; polytopal rearrangement; ring-opening metathesis polymerization (ROMP); stereochemistry
Categories
Funding
- NSF [CHE-1362763]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1362763] Funding Source: National Science Foundation
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Readily accessible and easy-to-handle Ru complexes capable of generating all-Z polynorbornene and polynorbornadiene by ring-opening metathesis polymerization (ROMP) with controllable selectivity, ranging from approximate to 50 to 95% syndiotactic, are introduced. It is demonstrated that the rate of non-metathesis based polytopal isomerization and levels of syndiotacticity may be fine-tuned by the adjustment of monomer concentration and catalyst's steric and electronic characteristics.
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