Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 47, Pages 14590-14594Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201606856
Keywords
copper complex; fullerenes; guanidine; heterocycles; macrocycle
Categories
Funding
- NNSFC [21272013, 21132007]
- MOST [2015CB856600]
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A 14-membered heterocycle is created on the C-60 cage skeleton through a multistep procedure. Key steps involve repeated PCl5-induced hydroxylamino N-O bond cleavage leading to insertion of nitrogen atoms, and also piperidine-induced peroxo O-O bond cleavage leading to insertion of oxygen atoms. The hetero atoms form one pyrrole, two pyran, and one diazepine rings in conjunction with the C-60 skeleton carbon atoms. The fullerene-based macrocycle showed unique reactivities towards fluoride ion and copper salts.
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