Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 32, Pages 9259-9261Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603741
Keywords
crystal structures; density functional calculations; halogen molecules; Raman spectroscopy; weakly coordinating anions
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Funding
- ERC
- DFG
- Polish Ministry of Science and Higher Education [895/MOB/2012/0]
- EU European Regional Development Fund within the Operational Programme Innovative economy [POIG.02.02.00-14-024/08-00]
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The perfluorohexane-soluble and donor-free silver compound Ag(A) (A= Al(ORF)(4); R-F = C(CF3)(3)) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen-silver complexes Ag(Cl-2)A, Ag(Br-2)A, and Ag(I-2)A derived from the soluble silver compound Ag(A) (characterized by single-crystal/powder XRD, Raman spectra, and quantum-mechanical calculations).
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