Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 15, Pages 4679-4682Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511053
Keywords
crystal engineering; host-guest systems; noncovalent interactions; peptoids; supramolecular chemistry
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Funding
- European Union [PIRSES-GA-2012-319011]
- University of Salerno (FARB)
- Italian MIUR [PRIN 20109Z2XRJ_006]
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A peptidomimetic compound undergoes a reversible single-crystal-to-single-crystal transformation upon guest release/uptake with the transformation involving a drastic conformational change. The extensive and reversible alteration in the solid state is connected to the formation of an unprecedented CH- zipper which can reversibly open and close (through the formation of CH- interactions), thus allowing for guest sensing.
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