Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 29, Pages 8367-8370Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603191
Keywords
asymmetric synthesis; cyclodextrins; homogeneous catalysis; palladium; polymerization
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Funding
- Japan Society for the Promotion of Science (JSPS)
- [25109517]
- Grants-in-Aid for Scientific Research [26620093, 15H00925] Funding Source: KAKEN
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Cationic Pd-II monophosphine complexes derived from alpha- and beta-cyclodextrins (CDs) promote the homopolymerization of styrene under carbon monoxide pressure. Although reversible CO coordination takes place under catalytic conditions according to C-13 NMR studies with C-13-enriched CO, both complexes catalyze the formation of CO-free styrene polymers. These macromolecules display optical activity as a result of the presence of stereoregular sequences within the overall atactic polymer.
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