Journal
TRIBOLOGY INTERNATIONAL
Volume 131, Issue -, Pages 1-10Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.triboint.2018.10.013
Keywords
Polyimide; Amine-functionalized graphene nanosheets; Covalent bonds; Tribological properties
Categories
Funding
- National Natural Science Foundation of China [51875330, 51803081, 51103065]
- Tribology Science Fund of State Key Laboratory of Tribology [SKLTICF17B08]
- Project National United Engineering Laboratory for Advanced Bearing Tribology [201806]
- Postgraduate Research &Practice Innovation Program of Jiangsu Province [KYCX18_2233]
- Jiangsu Province [Surencaiban [2015] 26]
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The novel polyimide (PI) nanocomposites that possess outstanding strength and high tribological performance were fabricated using different contents of amine-functionalized graphene nanosheets (AGNS) via in-situ polymerization. The AGNS was successfully prepared by condensation reaction and nitroreduction. Compared with properties of pure PI or PI/graphene nanosheets (GNS) blends, PI/AGNS nanocomposites exhibit distinguished improvement on thermal stability, mechanical properties and tribological performance due to the strong covalent bonds between AGNS and PI. Especially, PI/AGNS-0.5wt% nanocomposites revealed the extraordinary tribological properties as friction coefficient and wear rate decreased by 41.9% and 76.2% under dry sliding condition, respectively. The resultant PI/AGNS nanocomposites owned the combined excellent tribological and mechanical properties, demonstrating their potential applications in wear-resistant materials and other high-performance areas.
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