Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 51, Pages 15779-15782Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607075
Keywords
amidinates; luminescence; N-heterocyclic carbenes; OLEDs; platinum
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Funding
- BASF SE (Ludwigshafen)
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Binuclear (CC)-C-boolean AND* cyclometalated NHC platinum(II) compounds with bridging amidinate ligands were synthesized to evaluate their photophysical properties. Their three-dimensional structures were determined by a combination of 2D NMR experiments, mass spectrometry, DFT calculations, and solid-state structure analysis. The bridging amidinate ligands enforce short distances between the platinum centers of the two cyclometalated structures, which gives rise to extraordinary photophysical properties.
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