Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 55, Issue 47, Pages 14557-14562Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604784
Keywords
black phosphorus; charge transfer; functionalization; noncovalent interactions; stability
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Funding
- European Union Seventh Framework Programme [604391]
- Deutsche Forschungsgemeinschaft (DFG) [SFB 953]
- Interdisciplinary Center for Molecular Materials (ICMM)
- Graduate School Molecular Science (GSMS)
- ERC Starting Investigator Award STEMOX [239739]
- Fundacion BBVA
- EU [FP7/2013-IEF-627386]
- European Research Council (ERC) [239739] Funding Source: European Research Council (ERC)
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Black phosphorus (BP) was functionalized with organic moieties on the basis of liquid exfoliation. The treatment of BP with electron-withdrawing 7,7,8,8-tetra-cyano-p-quinodimethane (TCNQ) led to electron transfer from BP to the organic dopant. On the other hand, the noncovalent interaction of BP with a perylene diimide was mainly due to van der Waals interactions but also led to considerable stabilization of the BP flakes against oxygen degradation.
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