4.4 Article

Gold/photoredox-cocatalyzed atom transfer thiosulfonylation of alkynes: Stereoselective synthesis of vinylsulfones

Journal

TETRAHEDRON LETTERS
Volume 60, Issue 13, Pages 916-919

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.02.039

Keywords

Sulfur chemistry; Radical reaction; Photocatalysis

Funding

  1. National Natural Science Foundation of China [21572118, 21750110444]
  2. Tang Scholar Award from Shandong University

Ask authors/readers for more resources

We report a gold and photoredox combined radical approach for the rapid synthesis of thio-functionalized vinylsulfones from alkynes. Key features of this method include very mild conditions, broad substrate scope, excellent regio- and stereoselectivties, and 100% atom economy. (C) 2019 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available