Journal
TETRAHEDRON LETTERS
Volume 60, Issue 6, Pages 501-503Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.01.014
Keywords
Click reaction; Azoles; 1,2,3-Triazole
Categories
Funding
- National Research Foundation (NRF) of South Africa
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Copper catalysed click reactions are excellent tools to generate various 1,2,3-triazole linked polytopic aromatic carboxylates, The general reaction route involves protection of the carboxylates before proceeding with the click reaction. These polycarboxylate azoles are conveniently prepared for potential utility as novel key building blocks for metal organic frameworks. In one case, the ligand crystallises into a solid structure containing 1D, 2D and 3D features, based on a zigzag 1D structure, a 'chicken mesh'-like 2D structure and a 3D structure with very well-defined channels. (C) 2019 Published by Elsevier Ltd.
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