Journal
TETRAHEDRON
Volume 75, Issue 24, Pages 3248-3252Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2019.03.035
Keywords
C-N bond formation; Nitroarene; Boronic acid; Phosphine
Categories
Funding
- NIH NIGMS [GM114547]
- MIT
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A method for the preparation of aryl- and heteroarylamine products by triethylphosphine-mediated deoxygenative coupling of nitroarenes and boronic acids is reported. This method provides access to an array of functionalized (hetero)arylamine products from readily available starting materials under the action of an inexpensive commercial reagent. The developed triethylphosphine-mediated transformation highlights the capability of organophosphorus compounds to carry out this useful deoxygenative transformation without the necessity of any transition metal additives. (C) 2019 Elsevier Ltd. All rights reserved.
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