Journal
TETRAHEDRON
Volume 75, Issue 11, Pages 1541-1547Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2019.02.002
Keywords
Cobalt catalysis; Alkoxylation; Remote C-H activation; 1-Naphthylamine
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Funding
- National Natural Science Foundation of China [21102134, 21172200]
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An efficient protocol for cobalt (II)-catalyzed regioselective aryl C8-H bond alkoxylation of 1-naphthylamine derivatives with readily available alcohols has been developed, demonstrating an efficient approach to 8-alkoxy-1-naphthylamine derivatives with good functional group tolerance. Note that the picolinamide moiety as a bidentate directing group may play a key role in this regioselective transformation. (C) 2019 The Author(s). Published by Elsevier Ltd.
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