Journal
TETRAHEDRON
Volume 75, Issue 5, Pages 584-602Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.12.040
Keywords
Borylation; Carboboration; Diboron reagents; Photochemistry; Organoboron compounds; Rearrangements; Ring contraction
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Funding
- Welch Foundation [AX-1788]
- NSF [CHE-1455061]
- NIGMS [SC3GM105579]
- Max and Minnie Tomerlin Voelcker Fund
- Brown Foundation
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Photoinduced synthetic approaches to organoboron compounds have attracted significant attention in the recent years. Photochemical activation of organic molecules enables generation of reactive intermediates from a variety of precursors, resulting in borylation methods with improved and broader substrate scopes. The review summarizes recent developments in the area of photoinduced reactions of organoboron compounds with an emphasis on borylation of haloarenes, amine derivatives, and redox-active esters of carboxylic acids, as well as photoinduced rearrangements of organoboron compounds and photoinduced synthesis of organoboron compounds from alkenes and alkynes. (C) 2018 Elsevier Ltd. All rights reserved.
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