Oxygen isotope disequilibrium during serpentinite dehydration

Talc + olivine in metaperidotites result from the serpentinite breakdown due to increasing temperature in the Bergell contact aureole. Jack-straw olivine textures are present in close proximity to the serpentine breakdown reaction. As the intrusion is approached, the number of olivine crystals increases while the size of the crystals decreases; this feature documents increased overstepping with increased heating rates. Talc veinlets are observed in the outer parts of the talc-olivine zone and are interpreted to be pathways of fluid produced during devolatilization of serpentine. None of the talc-olivine oxygen isotope pairs analysed are in isotopic equilibrium with respect to the peak contact temperature. This implies that escaping fluids cannot be in equilibrium with both phases. Hence, the fluid produced by serpentine reaction does not directly reflect the protolith composition, and attention must be given to the reaction mechanism before interpreting fluid isotope composition.