Journal
SOIL USE AND MANAGEMENT
Volume 35, Issue 3, Pages 453-465Publisher
WILEY
DOI: 10.1111/sum.12497
Keywords
agrochemicals; denitrification; New Zealand; pastoral farming; spray and surface sowing; water quality
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Intensive agricultural activities could affect the dynamics and leaching of dissolved organic carbon (DOC) and nitrate from agricultural soils to receiving waters. This study investigated soil DOC dynamics immediately (0-12 days) after spraying a hill country perennial pasture with agrochemicals to establish a winter forage crop for supplementary feed production. Two treatments were examined-perennial pasture (without agrochemicals) and swede (Brassica napobrassica Mill.) cropping (after spraying with agrochemicals), both growing on a Typic Eutrudept. Soil samples were collected from various depths down to 1 m, before the application of agrochemicals (day 0) and 1, 6 and 12 days thereafter. Dissolved organic carbon concentration below the surface soil (<5 cm) was generally not altered by the agrochemicals. This was further proved by the isotopic monitoring of DOC leaching on this soil. Conversely, the agrochemicals significantly (p = 0.03) increased DOC concentration within the 0-5-cm soil depth on day 1, due to the direct contribution of organic molecules and/or displacement of organic compounds at adsorption sites by the agrochemicals; and on day 6, due to root necromass decomposition. The increase of nitrate in soil solution at this depth (0-5 cm) on days 6 and 12 suggests that the agrochemicals may have also enhanced nitrogen (N) mineralization in the surface soil. However, the significantly (p = 0.04) higher DOC/nitrate (molar ratio) of the agrochemical treatment suggests that the agrochemicals used for clearing out pasture before forage crop establishment could lead to a short-term increase in surface soil denitrification.
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