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Electrical Properties of Two-Dimensional Materials Used in Gas Sensors

Journal

SENSORS
Volume 19, Issue 6, Pages -

Publisher

MDPI
DOI: 10.3390/s19061295

Keywords

mathematical modeling; gas sensors; two-dimensional materials; graphene; transition metal dichalcogenides; field effect transistors; chemiresistors

Funding

  1. CONRICYT of the National Council of Science and Technology (CONACYT) from Mexico
  2. Thematic Network of Nanotechnology and Nanoscience of CONACYT, Mexico

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In the search for gas sensing materials, two-dimensional materials offer the possibility of designing sensors capable of tuning the electronic band structure by controlling their thickness, quantity of dopants, alloying between different materials, vertical stacking, and the presence of gases. Through materials engineering it is feasible to study the electrical properties of two-dimensional materials which are directly related to their crystalline structure, first Brillouin zone, and dispersion energy, the latter estimated through the tight-binding model. A review of the electrical properties directly related to the crystalline structure of these materials is made in this article for the two-dimensional materials used in the design of gas sensors. It was found that most 2D sensing materials have a hexagonal crystalline structure, although some materials have monoclinic, orthorhombic and triclinic structures. Through the simulation of the mathematical models of the dispersion energy, two-dimensional and three-dimensional electronic band structures were predicted for graphene, hexagonal boron nitride (h-BN) and silicene, which must be known before designing a gas sensor.

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