Journal
POLYMER COMPOSITES
Volume 40, Issue 9, Pages 3464-3471Publisher
WILEY
DOI: 10.1002/pc.25208
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- FAPESC/PAP
- CNPq
- CAPES
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This work aims to develop multifunctional biodegradable ternary nanocomposites with heat dissipation capability. The effects of adding hexagonal boron nitride (hBN), regarding phase morphology, near-infrared radiation (NIR) reflectance and thermal conductivity of poly(epsilon-caprolactone) (PCL) and poly(lactic acid) (PLA) blends were investigated. The hBN nanoparticles were selectively localized in the PCL phase. Scanning electron microscopy showed that the increased hBN concentration in the PCL/PLA blend led to a more fibrillar PLA phase and, after compression molding, its morphology presented a co-continuous structure. Adding hBN nanoplatelets increased the reflectance in the NIR region by 184%, the thermal conductivity of the PCL/PLA by 400%, and increased the blend's thermal stability. The co-continuous morphology could favor the heat flow, because it promotes the confinement of the hBN nanoplatelets in the PCL phase, favoring the conductive thermal pathway formation. POLYM. COMPOS., 40:3464-3471, 2019. (c) 2019 Society of Plastics Engineers
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