Journal
PLANTA MEDICA
Volume 85, Issue 9-10, Pages 701-707Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-0855-4051
Keywords
endolichenic fungi; Myrothecium inundatum; Stachybotryaceae; arborinane-type; riterpenes; diterpenes; cytotoxicity
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Funding
- National Natural Science Foundation of China [81673334]
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Two new arborinane-type triterpenes, myrotheols A (1) and B (2), two new arborinane-type glycosides, myrothesides C (3) and D (4), together with four known diterpenes (5-8) were isolated from the ethyl acetate extract of the endolichenic fungus Myrothecium inundatum. The structures of new compounds 1-4 were elucidated by NMR and MS analyses. The absolute configuration of 1 was assigned by a single-crystal X-ray diffraction experiment. Compounds 3 and 4 represent the first two natural 4-O-methyl-alpha-D-mannosides. Compounds 1-8 exhibited cytotoxicity against K562 and RKO human cancer cell lines.
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