Journal
ANALYTICAL METHODS
Volume 8, Issue 4, Pages 810-815Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ay02561c
Keywords
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Funding
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior CAPES [CAPES-DGU 243/11]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq, Brazil)
- Government of Spain [CTQ2011-23968, PHB2010-0018-PC]
- Regional Government of Valencia (Spain) [ACOMP/2013/072]
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A new procedure for determining trace concentrations of Mo in plants combining dispersive liquid-liquid microextraction and inductively coupled plasma optical emission spectrometry is proposed here. An automated discrete sample introduction system using a Flow Blurring (R) multiple nebulizer (FBMN) and a solenoid valve were used to insert an organic rich phase into the plasma. The experimental conditions for the microextraction procedure were: 0.5% m v(-1) of 8-hydroxyquinoline, pH 3.6 and 50 mu L of 1-undecanol as the extractant. A limit of detection of the instrument of 0.20 mu g L-1, a limit of detection of the procedure of 17 mu g kg(-1) and an enhancement factor of 246 were obtained employing the developed procedure. Three certified reference materials were used to check the accuracy and no significant differences were found at the 95% confidence level between certified and determined values. The developed procedure was also successfully applied to the determination of Mo in three different varieties of sugar cane leaves samples.
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