4.5 Article

Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration

Journal

ORGANOMETALLICS
Volume 38, Issue 5, Pages 1017-1020

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00933

Keywords

-

Funding

  1. Swarthmore College
  2. National Science Foundation [CHE-1664902]
  3. James H. Scheuer Summer Internship in Environmental Studies
  4. Frances Velay Women's Science Research Fellowship
  5. NSF [CHE-1337494]

Ask authors/readers for more resources

An aluminum complex of a tripodal tris(nitroxide)-based ligand has been prepared and characterized. The complex has the ability to participate in metal-ligand cooperative catalysis, which has been exploited for the hydroboration of both aldehydes and ketones. This represents new, transition-metal-like reactivity for an earth-abundant metal.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available