Journal
ORGANIC LETTERS
Volume 21, Issue 8, Pages 2731-2735Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00695
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Funding
- National Natural Science Foundation of China [NSFC-21572178, NSFC-21702162]
- Natural Science Basic Research Plan in Shaanxi Province of China [2017JM2006]
- Key Science and Technology Innovation Team of Shaanxi Province [2017KCT-37]
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An unprecedented cross-dehydrogenative-coupling (CDC) reaction of saturated aldehyde beta-C-H with arenes to form cinnamaldehydes via the cleavages of four C-H bonds has been developed. The reaction possesses complete E-stereoselectivity for the C = C double bond. The protocol is featured by atom and step economy, mild reaction conditions, and convenient operation.
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