Journal
ORGANIC LETTERS
Volume 21, Issue 7, Pages 2477-2481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00874
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Funding
- JSPS KAKENHI [JP26220803, JP17H06450]
- Japan Society for the Promotion of Science
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The facile synthesis of functionalized organoboron/silicon compounds by copper-catalyzed coupling of alkylsilyl peroxides and diboron/silylborane reagents is reported. The reactions proceed smoothly under mild, neutral conditions in short reaction times to generate organoboron/silicon compounds bearing a ketone moiety, which are useful synthetic intermediates that are otherwise difficult to access. The results of mechanistic investigations suggest the radical-mediated formation of carbon-boron and carbon-silicon bonds via beta-scission of alkoxy radicals.
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