4.8 Article

Zwitterionic nido-Carborane-Fused Phospholes

Journal

ORGANIC LETTERS
Volume 21, Issue 7, Pages 2273-2276

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00562

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Funding

  1. National Science Foundation of China [21672193, 21272218]
  2. Zhengzhou University of China

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Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key influence of the zwitterionic structure on the photophysical properties.

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