Journal
ORGANIC LETTERS
Volume 21, Issue 7, Pages 2449-2452Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00764
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Funding
- Key Research Program of the Frontier Sciences of the CAS [QYZDB-SSW-SMC026]
- NSFC [21672224]
- Government of Yunnan Province [2017FA002]
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Aromatic enamide and enecarbamate as a novel type of nucleophile in the asymmetric allylation of branched, racemic allylic alcohols to give homoallylic ketones has been described. Enabled by Carreira's chiral Ir (P, olefin) complex, the reactions proceed in good yields with excellent enantioselectivities.
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