Journal
ORGANIC LETTERS
Volume 21, Issue 4, Pages 1021-1025Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b04041
Keywords
-
Categories
Funding
- Soonchunhyang University
- Basic Science Research Program through the National Research Foundation of Korea [NRF-2016R1D1A1B03933723]
Ask authors/readers for more resources
Electrochemical oxidative radical selenylation/ 1,2 -carbon migration and Dowd-Beckwith-type ring-expansion sequences of alkenylcyclobutanols were developed in this study. This approach is environmentally benign and uses shelf-stable diselenides as selenium radical precursors and electrons as oxidizing reagents. The present protocol offers a facile way to prepare beta-selenated cyclic ketone derivatives. Under Dowd-Beckwith-type rearrangement, it can afford the corresponding one-carbon ring-expanded ketones.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available