Journal
ORGANIC LETTERS
Volume 21, Issue 6, Pages 1755-1759Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00323
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Funding
- School of Physical Sciences
- National Science Foundation
- Allergan Summer Undergraduate Research Program
- UCI University Research Opportunities Program
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A concise total synthesis of (+/-)-pestalachloride C and (+/-)-pestalachloride D was achieved through a Knoevenagel/hetero-Diels-Alder cascade reaction to test the nonenzymatic biosynthetic hypothesis of Shao, Wang, and co-workers. The cascade reaction generates a mixture of racemic indano[2,1-c]chromans like those found in the natural products.
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